Here is a batch of articles and links concerning the spray-on process for making astronomical mirrors reflective using protected silver solutions.
Long ago, I translated Foucault’s monograph on making paraboloidal, silvered astronomical mirrors. Part of his article described the process that he and Steinheil developed for silvering, which involved using silver nitrate solutions and various other reagents. It looked quite tricky, and also required further polishing! Plus, our telescope making workshop here in Washington DC had a Navy surplus vacuum chamber that was (and still is) quite effective at putting on good-quality, inexpensive aluminum coatings for any mirror up to 12.5″ diameter.
However, I and a couple of other ATMers (Bill R and Oscar O) are working on mirrors in the 16 to 18 inch range, and they simply won’t fit. So I was quite intrigued to watch how Peter Pekurar and some other folks coated a couple of rather large mirrors right in front of a small crowd of onlookers in a tent at this summer’s Stellafane.
I have a few videos on my webpage (here).
What is really, really amazing is that the webpage by Pekurar and Banich also has interferograms showing that the overcoating has absolutely no effect on the sub-microscopic, geometrical figure of the mirror! Unfortunately, it’s only effective against chemical attack, not against dirty fingers or scratches. They also did some careful experiments on reflectivity at various wavelengths with various treatments of the surface.
A couple of local ATMers and at least one professional at Goddard Space Flight Center have told me about their experiments with the process; they found that it is easy to mess up if you aren’t stringently clean and also easy to waste materials.